Solvolytic Reactivity of 1-Trifluoromethyl-1-phenylethyl Tosylate. Formation of a Highly Destabilized Carbonium Ion

DOI: 10.1021/ja00365a037

Source and publish data:

Journal of the American Chemical Society p. 207 - 211 (1982)

Update date:2022-08-03

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Authors:

Allen, Annette D.

Jansen, Michael P.

Koshy, Kalavelil M.

Mangru, Nevindra N.

Tidwell, Thomas T.

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Article abstract of DOI:10.1021/ja00365a037

The solvolytic rate constants of 1-trifluoromethyl-1-phenylethyl tosylate (2) in solvents of widely different ionizing power and nucleophilicity are linearly related with slope m_OTs = 1.01 to the rate of 2-adamantyl tosylate in the same solvent

Full text of DOI:10.1021/ja00365a037

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