Tetrahedron Letters p. 1085 - 1088 (1990)
Update date:2022-08-29
Topics:
Glass, Timothy E.
Leber, Phyllis A.
Gas-phase pyrolysis of theendo-vinyl epimer (1A) of the title compound at 275°C affords predominantly 3-(2-methyl-2-butenyl)cyclopentene (presumably the Z isomer), a direct [1,5]-hydrogen shift product, whereas the exo-vinyl epimer (IB) favors the fragmentation products, cyclopentene and isoprene.
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