Journal of the American Chemical Society p. 1802 - 1805 (1981)
Update date:2022-08-11
Topics:
Jackson, Robert L.
Pellerite, Mark J.
Brauman, John I.
We report the formation of the azide anion, N3-, in the gas phase using azidotrimethylsilane as the source.The azide anion is formed as a product of a fast ion-molecule reaction between the trimethylsilylnitrene anion, (CH3)3SiN-, and azidotrimethylsilane.A photodetachnemt treshold for N3- is obtained which can be equated with the adiabatic electron affinity of the azide radical, N3, giving EA = 62.1 +/- 2.8 kcal/mol.
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