Tetrahedron Letters p. 3579 - 3582 (1992)
Update date:2022-08-17
Topics:
Hoffman, Robert V.
Kim, Hwa-Ok
A new approach to ketomethylene and hydroxymethylene peptide isosteres has been developed which is simple, direct, and highly convergent.A key feature is construction of the central bond of a γ-keto ester by alkylation of a t-butyl β-keto ester with an α-bromo ester.
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