Iron- and Manganese-porphyrin Catalysed Aziridination of Alkenes by Tosyl- and Acyl-iminoiodobenzene

DOI: 10.1039/c39840001161

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1161 - 1163 (1984)

Update date:2022-08-17

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Authors:

Mansuy, Daniel

Mahy, Jean-Pierre

Dureault, Annie

Bedi, Gustave

Battioni, Pierrette

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Article abstract of DOI:10.1039/c39840001161

N-Substituted aziridines are formed by Fe- or Mn-porphyrin catalysed reactions of PhI=NR compounds (R = tosyl or COCF3) with alkenes; the stereochemical characteristics of these reactions are very different from those of the analogous epoxidation of alkenes by PhI=O.

Full text of DOI:10.1039/c39840001161

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