(Trifluoroacetimidoyl)lithiums and Their Reaction with Electrophiles

DOI: 10.1021/jo00083a016

Source and publish data:

Journal of Organic Chemistry p. 758 - 761 (1994)

Update date:2022-08-11

Topics:

Authors:

Watanabe, Hisayuki

Yan, Fengyang

Sakai, Takashi

Uneyama, Kenji

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Article abstract of DOI:10.1021/jo00083a016

N-Aryltrifluoroacetimidoyl iodides have been lithiated with n-butyllithium in ether.Because of the highly ionic nature of a carbon-lithium bond, the imidoyl carbanions are only stable below -60 deg C.The reaction temperature, solvent, and steric bulkiness

Full text of DOI:10.1021/jo00083a016

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Product name:Propanoic acid, 2-[(2,6-dimethylphenyl)imino]-3,3,3-trifluoro-, ethyl ester

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