Mechanism and utility of the dirhenium decacarbonyl catalyzed formation of silyl ethers

DOI: 10.1016/S0040-4039(00)61183-8

Source and publish data:

Tetrahedron Letters p. 5041 - 5044 (1992)

Update date:2022-08-16

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Authors:

Barton Barton

Kelly Kelly

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Article abstract of DOI:10.1016/S0040-4039(00)61183-8

A mechanism for dirhenium decacarbonyl catalyzed formation of silyl ethers is proposed. This reaction is a good alternative to the standard silylation procedure involving the use of more expensive silyl chlorides; even tertiary silyl ethers are readily formed.

Full text of DOI:10.1016/S0040-4039(00)61183-8

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