ANOMALOUS STEREOCHEMISTRY OF GASE-PHASE ACID-INDUCED RING OPENING IN 1-PHENYLCYCLOHEXENE OXIDE

DOI: 10.1016/S0040-4039(00)95522-9

Source and publish data:

Tetrahedron Letters p. 3393 - 3396 (1987)

Update date:2022-08-11

Topics:

Authors:

Crotti, P.

Macchia, F.

Pizzabiocca, A.

Renzi, G.

Speranza, M.

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Article abstract of DOI:10.1016/S0040-4039(00)95522-9

The first experimental evidence for an entropy-driven frontside displacement in a gas-phase cationic nucleophilic substitution has been provided by the results concerning the ring opening of 1-phenylcyclohexene oxide catalized by gaseous acids.

Full text of DOI:10.1016/S0040-4039(00)95522-9

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