Generation of a Lewis Acid Activated Formaldimine and Its Reaction with Enol Silyl Ethers. N-Unsubstituted Aminomethylation

DOI: 10.1021/jo00052a005

Source and publish data:

Journal of Organic Chemistry p. 7009 - 7010 (1992)

Update date:2022-08-16

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Authors:

Tanino, Keiji

Takahashi, Mitsumasa

Murayama, Koichi

Kuwajima, Isao

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Article abstract of DOI:10.1021/jo00052a005

N-(Trimethylsilyl)formaldimine-AlCl3 complex 2b was generated by treating (trimethylsilyl)methyl azide with AlCl3.The reaction of 2b with various kinds of enol triisopropylsilyl ethers afforded α'-aminomethylated enol silyl ethers in good yields.

Full text of DOI:10.1021/jo00052a005

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