The synthesis and reactions of Mn and Re formyl complexes, fac-(P-P)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3

DOI: 10.1016/0022-328X(94)88015-8

Source and publish data:

Journal of Organometallic Chemistry p. 113 - 118 (1994)

Update date:2022-08-29

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Authors:

Mandal, Santosh K.

Krause, Jeanette A.

Orchin, Milton

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Article abstract of DOI:10.1016/0022-328X(94)88015-8

Treatment of the salts fac-<(P-P)M(CO)4> (M=Mn, Re; P-P=dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield.Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydride

Full text of DOI:10.1016/0022-328X(94)88015-8

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