Tetrahedron Letters p. 2901 - 2904 (1983)
Update date:2022-08-17
Topics:
Medici, Alessandro
Fantin, Giancarlo
Fogagnolo, Marco
Dondini, Alessandro
2-Trimethylsilylthiazole (1) undergoes ipso-substitution of the silyl group with various acyl chlorides and ethyl chloroformate affording 2-acylthiazoles (2)-(5) but adds by the carbon-silicon bond to the carbonyl group of aldehydes yielding thiazol-2-yl-trimethylsiloxy-methane derivates (7).
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