TRIMETHYLPHOSPHITE DERIVATIVES OF THE MIXED COBALT-IRIDIUM TETRANUCLEAR CLUSTER Co2Ir2(CO)12

Article abstract of DOI:10.1016/S0022-328X(00)85575-8

Up to four carbonyl groups of Co2Ir2(CO)12 have been replaced by trimethylphosphite to form tetranuclear clusters of formula Co2Ir2(CO)12-nn.The clusters do not exhibit the redistribution of the metal core which is observed in the case of mixed c