14543-09-0

Basic information

• Product Name: dichlorocobalt
• Synonyms: dichlorocobalt
• CAS NO: 14543-09-0
• Molecular Formula: Cl2Co
• Molecular Weight: 0
• Mol File: 14543-09-0.mol

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: dichlorocobalt(CAS DataBase Reference)
• NIST Chemistry Reference: dichlorocobalt(14543-09-0)
• EPA Substance Registry System: dichlorocobalt(14543-09-0)

Safety Data

• Hazardous Substances Data: 14543-09-0(Hazardous Substances Data)

Usage

Uses

Radioactive agent.

InChI:InChI=1/2ClH.Co/h2*1H;/q;;+2/p-2/i;;1+1

Upstream product

• 7440-48-4 cobalt 
• 759403-02-6 cobalt(II) carbonate 
• 1112-67-0 tetrabutyl-ammonium chloride 
• 10545-99-0 sulfur dichloride 
• 56-23-5 tetrachloromethane 
• 7782-50-5 chlorine 
• 98-87-3 benzylidene dichloride 
• 71-48-7 cobalt(II) acetate 
• 75-36-5 acetyl chloride 
• 7719-09-7 thionyl chloride 
• 75-44-5 phosgene 
• 7647-01-0 hydrogenchloride 
• 75-77-4 chloro-trimethyl-silane 
• 12078-25-0 dicarbonylcyclopentadienylcobalt 

Downstream Products

• 243459-59-8 Co(C₄₈H₂₈N₈) 
• 243459-72-5 Co(C₄₈H₂₈N₈) 
• 26040-38-0 Co(C₄H₇N₂O₂)2(H₂NC₆H₅)2⁽¹⁺⁾*Cl^(1-)=[Co(C₄H₇N₂O₂)2(H₂NC₆H₅)2]Cl 
• 15218-68-5 Co(C₄H₇N₂O₂)2(H₂NC₆H₄OCH₃)2⁽¹⁺⁾*Cl^(1-)=[Co(C₄H₇N₂O₂)2(H₂NC₆H₄OCH₃)2]Cl 
• 22541-63-5 cobalt(III) 
• 84042-70-6 bis(2,4-pentanedionedihydrazone)cobalt(II) chloride 
• 78654-06-5 (C₂H₅)4N⁽¹⁺⁾*Co(P(C₆H₅)3)Cl₂Br^(1-)=(C₂H₅)4N[Co(P(C₆H₅)3)Cl₂Br] 
• 14726-62-6 CoCl2(PCy3)2 

Relevant articles and documents

Aluminum halide-cobalt halide polynuclear complexes active in low-temperature conversion of alkanes: Formation, molecular structures, and IR spectra

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The compression behavior of delafossite-type metallic oxide PdCoO 2 below 10 GPa has been investigated by in situ high pressure X-ray diffraction measurement using synchrotron radiation. It is found that the delafossite-type structure of PdCoO2 is stable below 10 GPa. It should be noted that compression behavior of PdCoO2 is anisotropic. Pressure dependence of the lattice parameters indicates that the a-axis is more compressible than the c-axis. The lattice parameter ratio c/a in the hexagonal unit increases with increasing pressure. The calculated zero-pressure bulk modulus is 224 GPa. It is found that the above characteristic compression behaviors of PdCoO2 are the same as those of the delafossite CuFeO2. The compressibilities of the a-axis of both PdCoO 2 and CuFeO2 are highly different although those of the c-axis are almost the same.

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New complexes of 4-[(4-fluorophenyl)amino]-4-oxobut-2-enoic acid with selected transition metal ions: Synthesis, thermal, and magnetic properties

Complexes of 4-[(4-fluorophenyl)amino]-4-oxobut-2-enoic acid, HL, with Mn(II), Co(II), Ni(II), Cu(II), Nd(III), Gd(III), and Er(III) were synthesized and characterized by various physico-chemical methods: elemental analysis, FT-IR, TG, DTG, DSC, TG/FT-IR, XRF, XRD, and magnetic measurements using the Gouy’s method and a SQUID-VSM magnetometer. The complexes were found to be hydrates (except Er(III) complex) containing 1 to 4 molecules of water. The carboxylate groups acted as bidentate ligands.

Mixed-Ligand Cobalt(III) Complexes of a Naturally Occurring Coumarin and Phenanthroline Bases as Mitochondria-Targeted Dual-Purpose Photochemotherapeutics

The bioessential nature of cobalt and the rich photochemistry of its coordination complexes can be exploited to develop potential next-generation photochemotherapeutics. A series of six novel mixed-ligand cobalt(III) complexes of the formulation [Co(B)2(L)]ClO4 (1-6), where B is an N,N-donor phenanthroline base, namely, 1,10-phenanthroline (phen in 1 and 4), dipyrido[3,2-d:2′,3′-f]quinoxaline (dpq in 2 and 5), and dipyrido[3,2-a:2′,3′-c]phenazine (dppz in 3 and 6), and L is an O,O-donor dianionic ligand derived from catechol (1,2-dihydroxybenzene, cat2-, in 1-3) or esculetin (6,7-dihydoxycoumarin, esc2-, in 4-6), have been prepared and characterized, and their light-triggered cytotoxicity has been studied in cancer cells. The single-crystal X-ray diffraction structures of complexes 1 (as PF6- salt, 1a) and 2 show distorted octahedral geometries around the cobalt(III) center formed by the set of N4O2 donor atoms. The low-spin and 1:1 electrolytic complexes 1-6 display a d-d transition around 700 nm. Complexes 4-6 with a coordinated esc2- ligand additionally display a π→ π? intraligand transition centered at 403 nm. Complexes 4-6 possessing a naturally occurring and photoactive esc2- ligand show high visible-light-triggered cytotoxicity against HeLa and MCF-7 cancer cells, yielding remarkably low micromolar IC50 values while being much less toxic under dark conditions. Control complexes 1-3 possessing the photoinactive cat2- ligand show significantly less cytotoxicity either in the presence of light or in the dark. The complex-induced cell death is apoptotic in nature caused by the formation of reactive oxygen species via a type 1 photoredox pathway. Fluorescence microscopy of HeLa cells treated with complex 6 reveals mitochondrial localization of the complex. A significant decrease in the dark toxicity of free esculetin and dppz base is observed upon coordination to cobalt(III). Complexes bind to calf-thymus DNA with significant affinity, but 6 binds with the greatest affinity. Complex 6 efficiently photocleaves supercoiled DNA to its nicked circular form when irradiated with visible light via a photoredox type 1 pathway involving hydroxyl radicals (HO?). Thus, complex 6 showing remarkable visible-light-triggered cytotoxicity but negligible toxicity in the dark is a good candidate for cancer photochemotherapy applications.

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