α-azidopolynitroalkanes. Synthesis and vibrational spectra

Article abstract of DOI:10.1007/BF02494372

Methods for the preparation of α-azidopolynitroalkanes by reactions of polynitroalkanes or α-(difluoroamino)polynitroalkanes with NaN₃ were developed. In the case of tetranitromethane, one or two nitro groups can be substituted, depending on the reaction conditions. The reaction of 1,1,1-trinitroethane with NaN₃ affords nitro-1,2,3-triazole, together with 1-azido-1,1-dinitroethane. The IR spectra of α-azidopolynitroalkanes were studied.