Utility of Phosphonium-Substituted Ester Enolates as Synthetic Intermediates. A Novel Trialkylphosphine-Catalyzed Rearrangement of Allylic Acrylates

DOI: 10.1021/jo00054a004

Source and publish data:

Journal of Organic Chemistry p. 299 - 300 (1993)

Update date:2022-08-16

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Authors:

Hanamoto, Takeshi

Baba, Yoshiyasu

Inanaga, Junji

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Article abstract of DOI:10.1021/jo00054a004

A novel Ireland-type <3,3> rearrangement which utilizes a catalytic amount of a trialkylphosphine with allylic acrylates has been developed as a synthetic entry into α-methylene-γ,δ-unsaturated carboxylic acids.

Full text of DOI:10.1021/jo00054a004

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