Journal of the Electrochemical Society p. 1493 - 1498 (1973)
Update date:2022-08-17
Topics:
Ulery
Reduction of alkyl halides at a Sn cathode in TEAX/MeCN results in mixed degrees of alkylation of this metal. Primary products include RSn, R//2Sn, and/or reactive polytins containing these units. Final products depend on environment and tend to be complicated mixtures. A direct synthesis with good yields of dibutyltin oxide and dioctyltin oxide results from aerating the catholyte. A mixture of alkyltin halides is formed in an undivided cell by the interaction of anode and cathode products; other products include the tetraethylammonium alkylhalostannates. Factors governing the course of cathodic alkylation are discussed.
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