Chemical Communications p. 2375 - 2376 (1996)
Update date:2022-08-30
Topics:
Yoshida, Shimon
Bryce, Martin R.
Chesney, Antony
1,3-Diselenolium cation salt 1 reacts with ammonia and iodine to afford the novel 1,4,2-diselenazine system 6 (40% yield) which fragments to yield dimethylcyanamide 8 and diselenin 9, presumably via intermediate 1,2-diselenete 7, which is trapped with dimethyl acetylenedicarboxylate to yield the cycloadduct 10.
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