Negative ion chemistry and the electron affinity of SF6

Article abstract of DOI:10.1063/1.443898

An extensive study of negative ion-molecule chemistry involving SF6 and SF6^- utilizing the room temperature flowing afterglow technique is reported.Based on a series of limit determinations, the recommended value of E.A.(SF6) is 1.0+/-0.2 eV.The discrepancy between this value and several previous determinations of E.A.(SF6) is discussed in terms of systematic experimental conditions and the formation of an excited state of SF6^-.A large number of reaction rate coefficients as well as qualitative observations of reaction mechanisms are presented.

Full text of DOI:10.1063/1.443898

Negative ion chemistry and the electron affinity of SF6
Gerald E. Streit
Citation: The Journal of Chemical Physics 77, 826 (1982); doi: 10.1063/1.443898
View online: http://dx.doi.org/10.1063/1.443898
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/77/2?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
160.36.178.25 On: Sun, 21 Dec 2014 04:48:26