Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1297 - 1302 (1982)
Update date:2022-08-16
Topics:
Gonzalez-Elipe, Agustin R.
Louis, Catherine
Che, Michel
Using the e.p.r. technique, the reaction at 77 K of an O- radical, formed by N2O adsorption on reduced MoO3/SiO2 samples, with CO or 13CO was followed, and possible to detect a CO2- radical (g1=2.0029, g2=2.0016, g3=1.9974, A1=199 G, A2=240 G, A3=207 G) which was stable at room temperature.This species reacted with O2 at 77 K to give rise to a radical of the type (O2COO)- (g1=2.0486, g2=2.0078, g3=2.0026, A1C=OG, A2C=4.8 G, A3C=6 G, A3O1=104 G, A3O11=40 G).At 150 K, it disappeared irreversibly, generating an O2- radical (g1=2.0175, g2=2.0097, g3=2.0040, A3O1=80 G, A3O11=70 G) similar to that formed by direct adsorption of oxygen on reduced MoO3/SiO2.
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