THE SYNTHESIS OF NEOSPOROL: A TRICHOTHECENE IN SEARCH OF A NATURAL PRODUCT

DOI: 10.1016/S0040-4039(00)82013-4

Source and publish data:

Tetrahedron Letters p. 1669 - 1672 (1988)

Update date:2022-08-11

Topics:

Authors:

Ziegler, Frederick E.

Nangia, Ashwini

Schulte, Gayle

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Article abstract of DOI:10.1016/S0040-4039(00)82013-4

The synthesis of neosporol 14, a yet to be discovered trichothecene, is described.The critical reaction is a highly diastereoselective Claisen rearrangement that sets the C5-C6 stereochemistry.

Full text of DOI:10.1016/S0040-4039(00)82013-4

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