Tetrahedron Letters p. 4197 - 4200 (1994)
Update date:2022-08-16
Topics:
Lygo, Barry
Swiatyj, Michael
Trabsa, Hassane
Voyle, Martyn
Short syntheses of Gabosines C (1) and E (3), starting from D-ribose are reported.The syntheses employ an intramolecular nitrile oxide cycloaddition to generate the carba-sugar skeleton, and result in the first total syntheses of unnatural (+)-Gabosine C and natural (+)-Gabosine E.
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