Synthesis of (+)-Gabosines C and E from D-Ribose

DOI: 10.1016/S0040-4039(00)73150-9

Source and publish data:

Tetrahedron Letters p. 4197 - 4200 (1994)

Update date:2022-08-16

Topics:

Authors:

Lygo, Barry

Swiatyj, Michael

Trabsa, Hassane

Voyle, Martyn

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Article abstract of DOI:10.1016/S0040-4039(00)73150-9

Short syntheses of Gabosines C (1) and E (3), starting from D-ribose are reported.The syntheses employ an intramolecular nitrile oxide cycloaddition to generate the carba-sugar skeleton, and result in the first total syntheses of unnatural (+)-Gabosine C and natural (+)-Gabosine E.

Full text of DOI:10.1016/S0040-4039(00)73150-9

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