Comparing α-carbanion-stabilizing ability of substituents using the Brook rearrangement

DOI: 10.1016/S0040-4039(98)01032-6

Source and publish data:

Tetrahedron Letters p. 5243 - 5246 (1998)

Update date:2022-08-16

Topics:

Authors:

Takeda, Kei

Ubayama, Haruka

Sano, Ayako

Yoshii, Eiichi

Koizumi, Toru

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Article abstract of DOI:10.1016/S0040-4039(98)01032-6

The α-carbanion-stabilizing ability of the phenylthio and trimethylsilyl groups was compared based on the relative rate of the base- catalyzed Brook rearrangement of the β-substituted α-silylallylalcohol.

Full text of DOI:10.1016/S0040-4039(98)01032-6

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