Tetrahedron Letters p. 6191 - 6194 (1994)
Update date:2022-08-17
Topics:
Choma, Christin T.
Kaestle, Karen
Akerfeldt, Karin S.
Kim, Ronald M.
Groves, John T.
DeGrado, William F.
An N-terminal cysteine is used to displace bromide from a bromoacetylated porphyrin to yield a thioether linkage between the peptide and the template. Unlike amide coupling reactions, this approach should be compatible with any peptide sequence provided there is only a single cysteine.
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