PALLADIUM-CATALYZED AROMATIC AMINATION OF ARYL BROMIDES WITH N,N-DIETHYLAMINO-TRIBUTYLTIN

DOI: 10.1246/cl.1983.927

Source and publish data:

Chemistry Letters p. 927 - 928 (1983)

Update date:2022-08-16

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Authors:

Kosugi, Masanori

Kameyama,Masayuki

Migita, Toshihiko

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Article abstract of DOI:10.1246/cl.1983.927

The reaction of N,N-diethylamino-tributyltin with aryl bromides in the presence of a catalytic amount of PdCl2(o-tolyl3P)2 gave N,N-diethylaminobenzene derivatives.The reaction is a new kind of amination different from ones through aryne or S_RN1 mechanism.

Full text of DOI:10.1246/cl.1983.927

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