Tetrahedron Letters p. 1523 - 1526 (1997)
Update date:2022-08-10
Topics:
Salunkhe, Ashok M.
Burkhardt, Elizabeth R.
A variety of prochiral ketones including phenyl, aralkyl, cycloalkyl, alkyl and tertiary alkyl are enantioselectively reduced with an oxazaborolidine catalyst (5 mol% of the Me-CBS) and N,N-diethylaniline·borane as the borane source. The enantioselectivity of the reduction produced secondary alcohols in the range of 90 to ≤99% ee.
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