Tetrahedron Letters p. 4965 - 4968 (1993)
Update date:2022-08-24
Topics:
Nukui, Seiji
Sodeoka, Mikiko
Shibasaki, Masakatsu
Indolizidine derivative 7 has been sythesized in up 86% ee by an asymmetric Heack reaction (Pd(O)-BPPFOH, Ag-exchanged zeolite) starting with prochiral alkenyl iodide 5. Conversion of 7 to δconiceine (9) is also described.
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