Journal of the Chemical Society. Chemical communications p. 775 - 777 (1981)
Update date:2022-08-11
Topics:
Nedelec, Lucien
Torelli, Vesperto
Hardy, Michel
α-Formylaminoacrylic esters, produced by the condensation of ethyl isocyanoacetate with 17-oxo-steroids have been reduced selectively to give the corresponding alcohols; the latter gave, in high yield, the hydroxyacetyl side-chain on acidic hydrolysis or the dihydroxy-acetone side-chain after appropriate oxidation and hydrolysis.
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(1977)
