SYNTHESIS OF HETEROPENTAMETALLIC CLUSTERS CONTAINING THREE DIFFERENT METALS: MCo3(CO)12M'L (M=Fe, Ru; M'=Cu, Ag)

Article abstract of DOI:10.1016/S0022-328X(00)99145-9

The new heteropentametalllic clusters MCo3(CO)12M'L (1-7), of trigonal bipyramidal structure, have been prepared from the tetrametallic anions ^- (M = Fe, Ru) and L --> M'Cl (M' = Cu, Ag; L = PPh3, ) or ⁺