Journal of the Chemical Society, Dalton Transactions p. 2891 - 2894 (1993)
Update date:2022-08-15
Topics:
Mallela, Siva P.
Myrczek, Joseph
Bernal, Ivan
Geanangel, Russell A.
The reaction of PbPh2Cl2 with two equivalents of LiA crystal-structure determination confirmed the presence of a Pb-Pb bond and the arrangement of the six substituents suggested that considerable steric strain between the C(SiMe3)3 group and the phenyls is present.Force-field calculations indicate that the structure of the expected product, Pba phenyl group migration and radical coupling to give a Pb-Pb bond are discussed.
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