A Novel Entry to Carbenoid Species via β-Ketosulfoxonium Ylides

DOI: 10.1039/c39930001434

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1434 - 1435 (1993)

Update date:2022-08-11

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Authors:

Baldwin, Jack E.

Adlington, Robert M.

Godfrey, Christopher R. A.

Gollins, David W.

Vaughan, Jason G.

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Article abstract of DOI:10.1039/c39930001434

In the presence of suitable rhodium(II) catalysts, lactam derived β-ketosulfoxonium ylides can be transformed to β-oxonitrogen heterocycles, e. g. substituted 4-oxopyrrolidine, via intermediates of carbenoid nature.

Full text of DOI:10.1039/c39930001434

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