Ozonolyses of O-alkylated ketoximes in the presence of carbonyl groups: A facile access to ozonides

Article abstract of DOI:10.1002/jlac.199719970715

Ozonolyses of O-methyl oximes of acyclic ketones (7, 10, 19) and of cyclic ketones (16, 24, 27, 31) in the presence of acyclic ketones (8, 9, 17) or of cyclic ketones (18, 25, 26, 31) gave the corresponding tetrasubstituted cross-ozonides (13, 21, 29, 32). Ozonolyses of O-methylated monooximes of 1,4-, 1,5-, and 1,6-dicarbonyl compounds (35b-f) gave the corresponding bicyclic ozonides 36b-f. VCH Verlagsgesellschaft mbH, 1997.