Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2755 - 2764 (1983)
Update date:2022-08-11
Topics:
Trenwith, Antony B.
The pyrolysis of propionitrile has been studied at seven temperatures over the range 789-850 K and pressures between 10 and 100 Torr.Under these conditions the principal reaction products which are formed by essentially homogeneous processes are hydrogen, hydrogen cyanide, methane, ethane, ethene, acetonitrile and acrylonitrile.For short reaction times (<3percent conversion) the products are formed at rates which do not vary noticeably with reaction time.A free radical chain mechanism has been proposed which accounts for all the above products.The chain initiating step is the reaction a resonance energy of 5.4 +/- 1.4 kcal mol-1 for the cyanomethyl radical.
Chengdu Pukang Biotechnology Co., Ltd
website:http://www.pu-kang.com
Contact:86-028-63976226
Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China
Contact:+86-0311-84455288-844
Address:Mayu Industrial Park, Jinzhou, Hebei, China.
NINGBO YINZHOU PRECISE COLOR CO.,LTD.
Contact:86-574-88139809 86-574-83033159
Address:Qiming Road,Yinzhou,Ningbo,China
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.
Contact:86-371-55219111
Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
Doi:10.1002/anie.201406098
(2014)Doi:10.1002/ejoc.201300526
(2013)Doi:10.1021/j100288a028
(1987)Doi:10.1002/zaac.200900269
(2010)Doi:10.1016/j.tet.2005.01.078
(2005)Doi:10.1021/ja00295a029
(1985)
