Journal of Physical Chemistry p. 5065 - 5067 (1994)
Update date:2022-08-11
Topics:
Zhu, T.
Yarwood, G.
Chen, J.
Niki, H.
FTIR spectroscopic studies of the photolysis (λ >/= 300 nm) of mixtures containing Cl2 and C2H2, cis-CHCl=CHCl, or trans-CHCl=CHCl were carried out in 700 Torr of N2 at 295 +/- 2 K.On the basis of the kinetic analysis of cis- and trans-CHCl=CHCl formed from C2H2, the branching ratio k1a/k1b has been determined to be 0.19 +/- 0.05.Cl + C2H2 (+M) -> cis=ClCH-CH (+M); Cl + C2H2 (+M) -> trans-ClCH=CH (+M).Implications of these results for our previously postulated mechanism of Cl atom initiated oxidation of C2H2 are discussed.
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