ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO BENZALDEHYDE CATALYZED BY A SMALL AMOUNT OF CHIRAL 2-AMINO-1-ALCOHOLS

DOI: 10.1016/S0040-4039(01)81300-9

Source and publish data:

Tetrahedron Letters p. 2823 - 2824 (1984)

Update date:2022-08-10

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Authors:

Oguni, Nobuki

Omi, Takao

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Article abstract of DOI:10.1016/S0040-4039(01)81300-9

The reaction of diethylzinc with benzaldehyde catalyzed by a small amount of chiral 2-amino-1-alcohols in toluene at room temperature gave optically active 1-phenylpropan-1-ol almost quantitatively in ca. 50percent ee.

Full text of DOI:10.1016/S0040-4039(01)81300-9

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