ORGANOCOBALT CLUSTER COMPLEXES. XXX. CARBON MONOXIDE LIGAND MIGRATION DURING THE SOLVOLYSIS OF HALOMETHYLIDYNETRICOBALT NONACARBONYL COMPLEXES. USEFUL SYNTHESES OF CARBOXYMETHYLIDYNETRICOBALT NONACARBONYL DERIVATIVES

Article abstract of DOI:10.1016/S0022-328X(00)93764-1

The reaction of aliphatic alcohols, ROH, and amines, RR'NH, with bromo- and chloro-methylidynetricobalt nonacarbonyl gives products of types ROC(O)CCo3(CO)9 and RR'NC(O)CCo3(CO)9, respectively.These reactions are accelerated by triethylamine.In the presen