Tetrahedron Letters p. 6701 - 6704 (1994)
Update date:2022-08-04
Topics:
Sato, Tsuneo
Otera, Junzo
The <2,3> sigmatropic rearrangement of γ-hydroxyalkyl γ-methoxyallyl sulfoxides occurs in a highly stereoselective manner to give δ-hydroxy-(E)-enals; a novel mechanism involving interaction between the hydroxy oxygen and the sulfinyl sulfur is proposed.
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