Journal of Organic Chemistry p. 11162 - 11167 (2016)
Update date:2022-08-10
Topics:
Wang, Dingyi
Zhang, Rongxing
Deng, Ruihong
Lin, Sen
Guo, Shengmei
Yan, Zhaohua
A copper-mediated oxidative functionalization of C(sp3)-H bonds with isoquinolines via a radical process without ligands was achieved. The present system exhibits a novel pathway for the preparation of N-alkyl (benzyl) isoquinolin-1(2H)-ones in moderate to high yields. In addition, this procedure provides a simple method to afford 5-oxaprotoberberinones and their derivatives in two steps.
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