Novel Asymmetric Ring-opening Reactions of Symmetrical N-Acylaziridines with Arenethiols Catalysed by Chiral Dialkyl Tartrate-Diethylzinc Complexes

DOI: 10.1039/c39940002699

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2699 - 2700 (1994)

Update date:2022-08-11

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Authors:

Hayashi, Masahiko

Ono, Kazuyuki

Hoshimi, Haruhisa

Oguni, Nobuki

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Article abstract of DOI:10.1039/c39940002699

The asymmetric ring-opening reaction of N-acylaziridines with arenethiols proceeds in the presence of chiral zinc complexes prepared from diethylzinc and L-(+)-diisopropyl tartrate (dipt) to afford trans-2-thio-(N-acylamino)cyclohexane in up to 88percent

Full text of DOI:10.1039/c39940002699

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