THE BARRIER FOR 1,2 HYDROGEN SHIFT IN DIALKYL CARBENES

DOI: 10.1016/S0040-4039(00)95234-1

Source and publish data:

Tetrahedron Letters p. 481 - 484 (1989)

Update date:2022-08-11

Topics:

Authors:

Stevens, Ian D. R.

Liu, Michael T. H.

Soundararajan, N.

Paike, N.

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Article abstract of DOI:10.1016/S0040-4039(00)95234-1

The products from the thermolysis of 4-diazirinopentanoic acid (2) allow the estimate of an experimental value for the E_a = 1.1 +/- 1 kcal.mol^-1 for the barrier height for 1,2 H shift in dialkyl carbenes.

Full text of DOI:10.1016/S0040-4039(00)95234-1

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