Chemical and Pharmaceutical Bulletin p. 477 - 480 (1996)
Update date:2022-08-03
Topics:
Iseki, Kalsuhiko
Kuroki, Yoshichika
Nagai, Takabumi
Kobayashi, Yoshiro
The hydrogenation of (E)-2-(trifluoromethyl)alk-2-en-1-ols catalyzed by Ru-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (Ru-BINAP) and Rh-BINAP was carried out with good enantiomeric excess (71-83% ee). Ru-BINAP-catalyzed hydrogenation converted 2-(trifluoromethyl)acrylic acid to the corresponding saturated acid whose esterification and reduction provided optically active 2-(trifluoromethyl)propan-1-ol in 80% ee.
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