Highly diastereoselective addition of methyl 2-(N-benzylamino)-1-cyclohexenecarboxylate to chiral acrylates

DOI: 10.1016/0957-4166(96)00024-9

Source and publish data:

Tetrahedron Asymmetry p. 425 - 426 (1996)

Update date:2022-07-30

Topics:

Authors:

Hervouet, Katia

Guingant, Andre

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Article abstract of DOI:10.1016/0957-4166(96)00024-9

Conjugate addition reaction of achiral methyl 2-(N-benzylamino)-1-cyclohexenecarboxylate 2 to chiral acrylates 4a,4b,4c led, after treatment of the primary adducts with sodium methoxyde, to α,α-disubstituted β-keto ester 1 with high enantiomeric excesses.

Full text of DOI:10.1016/0957-4166(96)00024-9

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Product name:(R)-1-(2-Methoxycarbonyl-ethyl)-2-oxo-cyclohexanecarboxylic acid methyl ester

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