Chemistry Letters p. 1163 - 1164 (1994)
Update date:2022-08-29
Topics:
Kimata, Yoshinori
Suzuki, Hiroshi
Satoh, Shin
Kuriyama, Akira
The novel electrochemical reaction of hydrosilane compounds was investigated for the synthesis of polysilanes.The product obtained by electrolysis of Methylphenylsilane 1a was an oligosilane of Mn=454 (GPC) in 60percent yield, which consisted of Si-Si bonds for the main chain.When diphenylsilane was electrolyzed in a similar manner as 1a, the major product was a dimer in 23percent yield.
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