Carbohydrate Research p. 85 - 92 (1995)
Update date:2022-08-11
Topics:
Gyoergydeak, Zoltan
Thiem, Joachim
Sodium hypochlorite oxidation catalysed by 2,2,6,6-tetramethylpiperidine 1-oxide (TEMPO) is shown to be a mild and efficient approach to the title uronates.In the gluco, galacto, allo, and 2-acetamido-2-deoxy-gluco series, the corresponding β- or α- and β-glycosyl azides could be smoothly oxidised and alternative preparations are compared to this access.Keywords: (D-Glycopyranosyl azide)uronates; Glycosyl azides; NaOCl-TEMPO oxidation
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