Tetrahedron p. 657 - 664 (1995)
Update date:2022-08-11
Topics:
Choi, Seung-Yong
Newcomb, Martin
Rate constants and Arrhenius functions for ring openings of the (trans-2-ethoxycarbonylcyclopropyl)methyl radical and the (trans-2-tert-butoxycarbonylcyclopropyl)methyl radical were determined by the PTOC-thiol method with PhSeH trapping.At 25 deg C, these radicals rearrange with rate constants of 7 and 12*1010 s-1, respectively.
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