HIGH DIASTEREOSELECTION IN THE CLAISEN REARRANGEMENT OF ENANTIOMERICALLY PURE BUTYROLACTONES

DOI: 10.1016/S0040-4039(00)87661-3

Source and publish data:

Tetrahedron Letters p. 3531 - 3534 (1982)

Update date:2022-08-18

Topics:

Authors:

Ziegler, Frederick E.

Thottathil, John K.

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Article abstract of DOI:10.1016/S0040-4039(00)87661-3

The Claisen rearrangement permits the stereoselective formation of butyrolactone 5b,c or 13b,c through the utilization of enantiomeric lactone 1a and enantiomeric alcohols 2b, ent-2b, 2c, and ent-2c.

Full text of DOI:10.1016/S0040-4039(00)87661-3

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