Molecular Crystals and Liquid Crystals p. 141 - 150 (2007)
Update date:2022-08-11
Topics:
Vaitkeviciene
Grazulevicius
Peciuraite
Grigalevicius
Jankauskas
Various diarylamino-substituted 1,3,5-triazine derivatives have been synthesized by Cu catalyzed Ullmann-type arylamino-aryl coupling reaction. Full characterization of the compounds structures by mass spectrometry, IR and electronic absorption, as well as 1H NMR spectroscopy is presented. Some of the compounds represent amorphous materials with glass transition temperatures exceeding 84C and with thermal decomposition starting at temperatures330C. The electron photoemission spectra of the materials were recorded and the ionisation potentials of ca. 5.3-5.8eV were established. Time-of-flight hole drift mobility of some diarylamino-substituted triazines molecularly dispersed in bisphenol Z polycarbonate approached 10-5cm2/Vs at high electric field.
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