Phenyldimethylsilyl as an Alcohol Surrogate in Intramolecular Diels-Alder Cycloaddition: Synthesis of α-Dictyopterol

DOI: 10.1021/jo00122a038

Source and publish data:

Journal of Organic Chemistry p. 5537 - 5539 (1995)

Update date:2022-08-16

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Authors:

Taber, Douglass F.

Bhamidipati, Rama S.

Yet, Larry

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Article abstract of DOI:10.1021/jo00122a038

α-Dictyopterol (1a), a sesquiterpene isolated from the essential oil of Dicytopteris divaricata, has been synthesized from bicyclic ketone 2, obtained by thermal cyclization of triene intermediate 11. The key observation is that the phenyldimethylsilyl gr

Full text of DOI:10.1021/jo00122a038

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