Preparation and Photolysis of 1-Cyano-glycopyranosyl Azides

DOI: 10.1016/0040-4039(95)00520-M

Source and publish data:

Tetrahedron Letters p. 3329 - 3332 (1995)

Update date:2022-08-29

Topics:

Authors:

Praly, Jean-Pierre

Stefano, Carmela Di

Descotes, Gerard

Faure, Rene

Somsak, Laszlo

Eperjesi, Istvan

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Article abstract of DOI:10.1016/0040-4039(95)00520-M

Treatment of 1-bromo-glycopyranosyl cyanides 1 and 4 with sodium azide in dimethyl sulfoxide gave 1-cyano-glycopyranosyl azides 2 and 5 in high yield, which on photolysis resulted in new oxazepine derivatives 3 and 6.

Full text of DOI:10.1016/0040-4039(95)00520-M

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