Inorganic Chemistry
Article
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(18) Note that a shift in rising edge to higher energies may also
indicate an increase in oxidation state; however, this primarily applies
to like-ligand systems.
(19) A weak trans-axial solvent ligand is typically not observed in
solution EXAFS measurements of transition metal-porphyrin
complexes.
(
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(
20) The error in the Mn−I distance is large (0.05−0.08 Å) because
of two factors: (i) the Mn and I do not share a bond and the
interatomic distance is long, and (ii) its scattering contribution
overlaps with the porphyrin robust multiple scattering
(
(
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22) Very recently, Yokota and Fujii reported mechanistic studies on
Reaction Chemistry of a Bis(iodosylbenzene)-Metalloporphyrin
Complex, [PhI(OAC)O] Mn TPP. A Complex Possessing a Five-
•
+
+
IV
the formation of Fe(IV)(O)(Porp) and [Fe(IV)(O)(Porp )]
2
species from its Fe(III)(OCl)(Porp) precursor; see: Yokota, S.;
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922.
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3
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Rhodium-Carbon Bond of κ -Coordinated 2-Phenylpyridine. Organo-
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T. Accelerated Oxygen Atom Transfer and C−H Bond Oxygenation
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(
Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Com-
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3
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(
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2
2
Intermediates by m-Chloroperoxybenzoic Acid. Angew. Chem., Int. Ed.
2000, 39, 3646−3649. (b) Nam, W.; Oh, S.-Y.; Lim, M. H.; Choi, M.-
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(
14) Abbreviations used: TDCPP, meso-tetrakis(2,6-dichlorophenyl)
porphinato dianion; TPFPP, meso-tetrakis(pentafluorophenyl)porphi-
nato dianion; TMP, meso-tetramesitylporphinato dianion; 13-TMC,
1
,4,7,10-tetramethyl-1,4,7,10-tetraazacyclotridecane.
15) Identical UV-vis spectrum and reactivity performance of 1
could be obtained in neat CH Cl at −60 °C. However, the solvent
(
2
2
system was optimized to be CH Cl /BuCN/TFE (v/v/v 5:5:1),
2
2
H
Inorg. Chem. XXXX, XXX, XXX−XXX