Ring opening of phenylaziridines with allylsilanes

DOI: 10.1016/0040-4039(96)01975-2

Source and publish data:

Tetrahedron Letters p. 8493 - 8496 (1996)

Update date:2022-08-11

Topics:

Authors:

Schneider, Marie-Reine

Mann, Andre

Taddei, Maurizio

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Article abstract of DOI:10.1016/0040-4039(96)01975-2

N-tosyl phenylaziridines are opened regioselectively with allylsilanes in presence of BF₃.ET₂O to form γ-amino olefins. During the reaction a formal [3+2] cycloaddition produced the corresponding pyrrolidines, amenable to the open chain compounds with TBAF.

Full text of DOI:10.1016/0040-4039(96)01975-2

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